Charge‐Driven Bioshield Remodels Diabetic Oral Microenvironment for Accelerated Wound Healing

Y Yajuan Xie (Department of Orthodontics National Center for Stomatology National Clinical Research Center For Oral Diseases National Engineering Laboratory for Digital and Material Technology of Stomatology Beijing Key Laboratory of Digital Stomatology Research Center of Engineering and Technology for Computerized Dentistry Ministry of Health NMPA Key Laboratory for Dental Materials Peking University School and Hospital of Stomatology Beijing China) Y Yunfan Zhang Y Yue Yang X Xiaomo Liu (Department of Orthodontics National Center for Stomatology National Clinical Research Center For Oral Diseases National Engineering Laboratory for Digital and Material Technology of Stomatology Beijing Key Laboratory of Digital Stomatology Research Center of Engineering and Technology for Computerized Dentistry Ministry of Health NMPA Key Laboratory for Dental Materials Peking University School and Hospital of Stomatology Beijing China) R Ruichu Zhang (Department of Orthodontics National Center for Stomatology National Clinical Research Center For Oral Diseases National Engineering Laboratory for Digital and Material Technology of Stomatology Beijing Key Laboratory of Digital Stomatology Research Center of Engineering and Technology for Computerized Dentistry Ministry of Health NMPA Key Laboratory for Dental Materials Peking University School and Hospital of Stomatology Beijing China) Y Yabo Wang (Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering) B Bo Li C Chao Ma H Hongjie Zhang (State Key Laboratory of Rare Earths) Y Yusai Zhou (Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China) B Bing Han K Kai Liu Y Yan Wei (National Engineering Laboratory for Digital and Material Technology of Stomatology, Beijing Laboratory of Biomedical Materials)

Abstract

ABSTRACT Diabetic chronic wounds, especially in the moist and mechanically dynamic oral environment, pose a significant therapeutic challenge due to neutrophil extracellular traps (NETs)‐mediated inflammation, biofilm infections, and extracellular matrix remodeling defects. To address this challenge, we develop a protein‐based adhesive bioshield, functioning through the combined action of physical blocking and electrostatic interaction, that simultaneously acts as a bacterial barrier and NETs scavenger, thereby reactivating the focal adhesion signaling. The protein's high‐density lysine residues establish a robust adhesion network that resists the dynamic oral environment while creating a persistent antibacterial bioshield. Notably, the high net charge of adhesive bioshield enables rapid NETs neutralization by electrostatically binding cell‐free DNA (cfDNA), which reduces local NETs levels and inflammatory responses. This NETs clearance subsequently alleviates inflammation‐mediated suppression of focal adhesion signaling, which coordinately accelerates diabetic wound healing through enhanced epithelial migration, endothelial proliferation, and angiogenesis. Overall, this study presents a charge‐driven therapeutic strategy that targets NETs‐mediated inflammation, offering an alternative approach for managing diabetic wounds in dynamic and wet environments.

Article Details

Volume / Issue Vol. 38, Issue 11
Published February 01, 2026
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (13)

Y

Yajuan Xie

Department of Orthodontics National Center for Stomatology National Clinical Research Center For Oral Diseases National Engineering Laboratory for Digital and Material Technology of Stomatology Beijing Key Laboratory of Digital Stomatology Research Center of Engineering and Technology for Computerized Dentistry Ministry of Health NMPA Key Laboratory for Dental Materials Peking University School and Hospital of Stomatology Beijing China

Y

Yunfan Zhang

Y

Yue Yang

X

Xiaomo Liu

Department of Orthodontics National Center for Stomatology National Clinical Research Center For Oral Diseases National Engineering Laboratory for Digital and Material Technology of Stomatology Beijing Key Laboratory of Digital Stomatology Research Center of Engineering and Technology for Computerized Dentistry Ministry of Health NMPA Key Laboratory for Dental Materials Peking University School and Hospital of Stomatology Beijing China

R

Ruichu Zhang

Department of Orthodontics National Center for Stomatology National Clinical Research Center For Oral Diseases National Engineering Laboratory for Digital and Material Technology of Stomatology Beijing Key Laboratory of Digital Stomatology Research Center of Engineering and Technology for Computerized Dentistry Ministry of Health NMPA Key Laboratory for Dental Materials Peking University School and Hospital of Stomatology Beijing China

Y

Yabo Wang

Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering

B

Bo Li

C

Chao Ma

H

Hongjie Zhang

State Key Laboratory of Rare Earths

Y

Yusai Zhou

Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China

B

Bing Han

K

Kai Liu

Y

Yan Wei

National Engineering Laboratory for Digital and Material Technology of Stomatology, Beijing Laboratory of Biomedical Materials