DNA Supramolecular Hydrogel Alters Exosomal microRNA Atlas and Paracrine Secretory Profile of MSCs to Promote Bone Remodeling and Ameliorate Osteoradionecrosis of the Jaw

Y Yue Li X Xue Li M Miaomiao Qiu Z Zhaowei Zhang L Lianqiang Dong (CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry Chinese Academy of Sciences Beijing P. R. China) Z Zhengyang Wei (Beijing Institute of Radiation Medicine Beijing P. R. China) L Lingwei Meng (Department of Prosthodontics, Peking University School and Hospital of Stomatology, National Center for Stomatology, National Clinical Research Center for Oral Diseases, National Engineering Research Center of Oral Biomaterials and Digital Medical Devices, Beijing Key Laboratory of Digital Stomatology, NHC Key Laboratory of Digital Stomatology NMPA Key Laboratory For Dental Materials Beijing P. R. China) Y Yuanjing Zheng (Beijing Institute of Radiation Medicine Beijing P. R. China) Y Yang Wang Y Yuanlin Liu (Beijing Institute of Radiation Medicine Beijing P. R. China) D Dongsheng Liu (Department of Chemistry) S Shaoxia Pan (Department of Prosthodontics, Peking University School and Hospital of Stomatology, National Center for Stomatology, National Clinical Research Center for Oral Diseases, National Engineering Research Center of Oral Biomaterials and Digital Medical Devices, Beijing Key Laboratory of Digital Stomatology, NHC Key Laboratory of Digital Stomatology NMPA Key Laboratory For Dental Materials Beijing P. R. China) Y Yi Zhang Y Yuanchen Dong (CAS Key Laboratory of Colloid Interface and Chemical Thermodynamics, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry)

Abstract

ABSTRACT Osteoradionecrosis of the jaw (ORNJ) is a severe complication of head and neck radiotherapy, characterized by a hostile tissue microenvironment that hinders healing. To address the limitations of mesenchymal stem cell (MSC) therapy, such as rapid dispersion and clearance, we developed an injectable, shear‐thinning DNA supramolecular hydrogel (DNASH) as a 3D scaffold. The DNASH matrix significantly prolonged the local retention of MSCs and their exosomes for over 3 weeks. Crucially, the scaffold actively reprogrammed the MSC secretome by modulating the FAK‑Integrin and Hippo‑YAP mechanotransduction pathways. This directed a shift toward a pro‐regenerative exosomal miRNA profile, notably enriching miR‑146a‑5p and reducing miR‑125b‑5p. In a murine ORNJ model, this MSC‐laden hydrogel orchestrated a coupled bone‐remodeling process, effectively clearing necrotic bone while stimulating robust osteogenesis. The treatment restored mandibular architecture, reduced systemic inflammation, and improved tissue homeostasis, presenting a clinically promising strategy for ORNJ repair.

Article Details

Volume / Issue Vol. 1, Issue 1
Published February 19, 2026
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (14)

Y

Yue Li

X

Xue Li

M

Miaomiao Qiu

Z

Zhaowei Zhang

L

Lianqiang Dong

CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry Chinese Academy of Sciences Beijing P. R. China

Z

Zhengyang Wei

Beijing Institute of Radiation Medicine Beijing P. R. China

L

Lingwei Meng

Department of Prosthodontics, Peking University School and Hospital of Stomatology, National Center for Stomatology, National Clinical Research Center for Oral Diseases, National Engineering Research Center of Oral Biomaterials and Digital Medical Devices, Beijing Key Laboratory of Digital Stomatology, NHC Key Laboratory of Digital Stomatology NMPA Key Laboratory For Dental Materials Beijing P. R. China

Y

Yuanjing Zheng

Beijing Institute of Radiation Medicine Beijing P. R. China

Y

Yang Wang

Y

Yuanlin Liu

Beijing Institute of Radiation Medicine Beijing P. R. China

D

Dongsheng Liu

Department of Chemistry

S

Shaoxia Pan

Department of Prosthodontics, Peking University School and Hospital of Stomatology, National Center for Stomatology, National Clinical Research Center for Oral Diseases, National Engineering Research Center of Oral Biomaterials and Digital Medical Devices, Beijing Key Laboratory of Digital Stomatology, NHC Key Laboratory of Digital Stomatology NMPA Key Laboratory For Dental Materials Beijing P. R. China

Y

Yi Zhang

Y

Yuanchen Dong

CAS Key Laboratory of Colloid Interface and Chemical Thermodynamics, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry