Evolution and Reconstruction of Air‐Electrode Surface Composition in Reversible Protonic Ceramic Cells: Mechanisms, Impacts on Catalytic Performance, and Optimization Strategies – A Review

Abstract

AbstractReversible protonic ceramic cells (R‐PCCs) are at the forefront of electrochemical conversion devices, capable of reversibly and efficiently converting chemical energy into electricity at intermediate temperatures (350–700 °C) with zero carbon emissions. However, slow surface catalytic reactions at the air‐electrode often hinder their performance and durability. The electrode surface is not merely an extension of the bulk structure, equilibrium reconstruction can lead to significantly different crystal‐plane terminations and morphologies, which are influenced by material's intrinsic properties and external reaction conditions. Understanding electrode surface evolution at elevated temperatures in water‐containing, oxidative atmospheres presents significant importance. In this review, a comprehensive summary of recent processes in applying advanced characterization techniques for high‐temperature electrode surfaces is provided, exploring the correlations between surface evolution and performance fluctuations by examining the structural evolution and reconstruction of various air‐electrode surfaces associated with degradation and activation phenomena, offering insights into their impact on electrode performance. Furthermore, reported strategies and recent advances in enhancing the electrochemical performance of R‐PCCs through engineering air‐electrode surfaces is discussed. This review offers valuable insights into surface evolution in R‐PCCs and is expected to guide future developments in high‐temperature catalysis, solid‐state ionics, and energy materials.