Ionoelastomer Synapses With Configurable Synaptic Plasticity

S Sijie Zheng Z Zhong‐Da Zhang (State Key Laboratory of Bioinspired Interfacial Materials Science Institute of Functional Nano and Soft Materials (FUNSOM) Soochow University Suzhou 215123 China) X Xiaowei Wang X Xiuyang Zou (School of Chemistry and Chemical Engineering Huaiyin Normal University Huaian China) Z Ziyang Liu Q Qingning Li (Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University) Y Ya‐Nan Zhong (State Key Laboratory of Bioinspired Interfacial Materials Science Institute of Functional Nano and Soft Materials (FUNSOM) Soochow University Suzhou 215123 China) S Sui‐Dong Wang (State Key Laboratory of Bioinspired Interfacial Materials Science Institute of Functional Nano and Soft Materials (FUNSOM) Soochow University Suzhou 215123 China) F Feng Yan (Materials Science and Engineering Program, School for Engineering of Matter, Transport and Energy)

Abstract

Abstract An organic heterostructure, composed of an ionoelastomer that comprises polycationic chains and mobile anions, and a semiconducting polymer, forms a new class of artificial synapses. These ionoelastomer synapses update their synaptic weights by modifying device conductance through the spatial redistribution of anions in response to electrical stimuli. The memory effect of these synapses is highly dependent on the specific anion species present, providing a unique means to modulate synaptic plasticity simply through anion selection. The continuously programmable and nonvolatile states of the selected ionoelastomer synapse are harnessed to emulate a soft neural network and perform the handwritten digit and fashion image recognition tasks, which achieve high recognition accuracies comparable to ideal numeric model but only using 16 discrete device states.

Article Details

Volume / Issue Vol. 37, Issue 44
Published November 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (9)

S

Sijie Zheng

Z

Zhong‐Da Zhang

State Key Laboratory of Bioinspired Interfacial Materials Science Institute of Functional Nano and Soft Materials (FUNSOM) Soochow University Suzhou 215123 China

X

Xiaowei Wang

X

Xiuyang Zou

School of Chemistry and Chemical Engineering Huaiyin Normal University Huaian China

Z

Ziyang Liu

Q

Qingning Li

Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Negative Carbon Technologies, Suzhou Key Laboratory of Soft Material and New Energy, College of Chemistry, Chemical Engineering and Materials Science, Soochow University

Y

Ya‐Nan Zhong

State Key Laboratory of Bioinspired Interfacial Materials Science Institute of Functional Nano and Soft Materials (FUNSOM) Soochow University Suzhou 215123 China

S

Sui‐Dong Wang

State Key Laboratory of Bioinspired Interfacial Materials Science Institute of Functional Nano and Soft Materials (FUNSOM) Soochow University Suzhou 215123 China

F

Feng Yan

Materials Science and Engineering Program, School for Engineering of Matter, Transport and Energy