Long‐Lifespan and High‐Rate Energy Storage Enabled by Lithium‐Free Batteries with External Li Supply
Abstract
Abstract Energy storage batteries are pivotal for enabling reliable integration of renewable energy systems, yet further advancements in their longevity and rate performance remain imperative. Lithium (Li)‐free cathode materials, while offering exceptional electrochemical stability, rate capability, and cost efficiency, face a critical limitation: the absence of active Li ions when paired with conventional graphite anodes. To address this challenge, a Li‐free battery design is presented that integrates a graphite|TiS 2 pouch cell architecture with a standard electrolyte modified by lithium trifluoromethanesulfinate (LiSO 2 CF 3 ). This additive serves as an in situ Li‐ion reservoir, electrochemically releasing Li ions during operation without generating deleterious residues or compromising structural integrity. The optimized cell achieves an unprecedented cycle life exceeding 14 000 cycles at a high current rate of 10C, alongside remarkable sustainability and cost‐effectiveness. This work establishes a practical pathway for deploying long‐lasting, fast‐charging Li‐free batteries in grid‐scale energy storage applications.
Article Details
Authors (5)
Xinwei Du
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Institute of Fiber Materials and Devices, Research Center of AI for Polymer Science, Collaborative Innovation Center of Chemistry for Energy Materials
Shu Chen
Ziyang Kang
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Institute of Fiber Materials and Devices, Research Center of AI for Polymer Science, Collaborative Innovation Center of Chemistry for Energy Materials
Zilong Zheng
Yue Gao