Mechanical Robust Nacre‐Mimetic Composites with Designable Cryptic Coloration and Electromagnetic Wave‐Transparent Performance

J Jun Pang (Department of Urology, Kidney and Urology Center, The Seventh Affiliated Hospital, Sun Yat-sen University) Z Zhen‐Bang Zhang (Institute of Innovative Materials Department of Chemistry Department of Materials Science and Engineering Shenzhen Key Laboratory of Sustainable Biomimetic Materials Guangming Advanced Research Institute Southern University of Science and Technology Shenzhen 518055 China) Z Ze‐Yu Wang (Tianjin Key Laboratory of Advanced Functional Porous Materials Institute for New Energy Materials and Low‐Carbon Technologies, School of Materials Science and Engineering Tianjin University of Technology Tianjin 300384 P. R. China) S Si‐Chao Zhang (New Cornerstone Science Laboratory Department of Chemistry Institute of Biomimetic Materials & Chemistry Anhui Engineering Laboratory of Biomimetic Materials Division of Nanomaterials & Chemistry Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei 230026 China) S Shao‐Meng Wen (New Cornerstone Science Laboratory Department of Chemistry Institute of Biomimetic Materials & Chemistry Anhui Engineering Laboratory of Biomimetic Materials Division of Nanomaterials & Chemistry Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei 230026 China) C Chen Cui H Huai‐Ling Gao (CAS Key Laboratory of Mechanical Behavior and Design of Materials Department of Modern Mechanics University of Science and Technology of China Hefei Anhui 230027 China) S Shu‐Hong Yu (New Cornerstone Science Laboratory Department of Chemistry Institute of Biomimetic Materials and Chemistry Anhui Engineering Laboratory of Biomimetic Materials Division of Nanomaterials and Chemistry Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei 230026 China)

Abstract

AbstractCeramic materials are widely used in various protective equipment owing to their excellent mechanical properties and chemical stability, while their applications are limited by monotonous color and poor toughness. Inspired by the colorful and tough natural shells, nacre‐mimetic alumina (Al2O3)‐based (NMA) composites are fabricated by proposing a dual‐oxide interface design strategy inspired by the hierarchical structure of natural nacre. The NMA composites achieve color regulation, providing possibilities for their application in camouflage protective armor. The fracture toughness of the optimal NMA composite is more than three times that of commercial Al2O3 ceramic. Simultaneously, the NMA composites have obvious advantages in terms of impact resistance compared with Al2O3 ceramic and polymer polymethyl methacrylate (PMMA). Additionally, the hierarchical structure of the NMA composites provides favorable structural conditions for transmission of electromagnetic (EM) waves at the frequency band of 18–26.5 GHz. These characteristics make the NMA composites potential protective materials for radar and communication equipment.

Article Details

Volume / Issue Vol. 37, Issue 20
Published May 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (8)

J

Jun Pang

Department of Urology, Kidney and Urology Center, The Seventh Affiliated Hospital, Sun Yat-sen University

Z

Zhen‐Bang Zhang

Institute of Innovative Materials Department of Chemistry Department of Materials Science and Engineering Shenzhen Key Laboratory of Sustainable Biomimetic Materials Guangming Advanced Research Institute Southern University of Science and Technology Shenzhen 518055 China

Z

Ze‐Yu Wang

Tianjin Key Laboratory of Advanced Functional Porous Materials Institute for New Energy Materials and Low‐Carbon Technologies, School of Materials Science and Engineering Tianjin University of Technology Tianjin 300384 P. R. China

S

Si‐Chao Zhang

New Cornerstone Science Laboratory Department of Chemistry Institute of Biomimetic Materials & Chemistry Anhui Engineering Laboratory of Biomimetic Materials Division of Nanomaterials & Chemistry Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei 230026 China

S

Shao‐Meng Wen

New Cornerstone Science Laboratory Department of Chemistry Institute of Biomimetic Materials & Chemistry Anhui Engineering Laboratory of Biomimetic Materials Division of Nanomaterials & Chemistry Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei 230026 China

C

Chen Cui

H

Huai‐Ling Gao

CAS Key Laboratory of Mechanical Behavior and Design of Materials Department of Modern Mechanics University of Science and Technology of China Hefei Anhui 230027 China

S

Shu‐Hong Yu

New Cornerstone Science Laboratory Department of Chemistry Institute of Biomimetic Materials and Chemistry Anhui Engineering Laboratory of Biomimetic Materials Division of Nanomaterials and Chemistry Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China Hefei 230026 China