Nanoscale Biodegradable Printing for Designed Tuneability of Vaccine Delivery Kinetics

D David J. Peeler (Department of Materials Department of Bioengineering and Institute for Biomedical Engineering Imperial College London London UK) R Rujie Sun (Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom) C Ceren Kütahya (Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom) P Patrick Peschke (Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom) K Kun Zhou (Key Laboratory of Animal Virology, Ministry of Agricultural and Rural Affairs of China and Zhejiang Provincial Engineering Research Center of Animal Biological Products, Department of Veterinary Medicine, Zhejiang University College of Animal Sciences) G Giulia Brachi (Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom) J Jonathan Yeow O Omar Rifaie‐Graham (Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom) J Jonathan P. Wojciechowski (Department of Physiology, Anatomy and Genetics, Department of Engineering Science, Kavli Institute for Nanoscience Discovery, University of Oxford, Sherrington Rd, Oxford OX1 3QU, U.K.) T Thomas F. F. Fernandez Debets (Department of Physiology, Anatomy and Genetics, Department of Engineering Science, Kavli Institute for Nanoscience Discovery, University of Oxford, Sherrington Rd, Oxford OX1 3QU, U.K.) V Vernon LaLone (Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom) X Xin Song K Krunal Polra (Department of Infectious Disease Faculty of Medicine Imperial College London South Kensington Campus London SW7 2AZ United Kingdom) P Paul F. McKay (Department of Infectious Disease Faculty of Medicine Imperial College London South Kensington Campus London SW7 2AZ United Kingdom) J John S. Tregoning R Robin J. Shattock M Molly M. Stevens

Abstract

Abstract Two‐photon polymerization (2PP) 3D printing enables top–down biomaterial synthesis with nanoscale spatial resolution for de novo design of monodisperse injectable drug delivery systems. Spatiotemporal Controlled Release Inks of Biocompatible polyEsters (SCRIBE) is a novel poly(lactic‐ co ‐glycolic acid)‐triacrylate resin family with sub‐micron resolution and tuneable hydrolysis that addresses the limitations of current 2PP resins. SCRIBE enables the direct printing of hollow microparticles with tuneable chemistry and complex geometries inaccessible to molding techniques, which are used to engineer controlled protein release in vitro and in vivo. SCRIBE microparticles are used to modulate antibody titers and class switching as a function of antigen release rate and extend these findings to enable a single‐injection vaccine formulation with extended antibody induction kinetics. Demonstrating how the chemistry and computer‐aided design of 2PP‐printed microparticles can be used to tune responses to biomacromolecule release in vivo opens significant opportunities for a new generation of drug delivery vehicles.

Article Details

Volume / Issue Vol. 37, Issue 15
Published April 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (17)

D

David J. Peeler

Department of Materials Department of Bioengineering and Institute for Biomedical Engineering Imperial College London London UK

R

Rujie Sun

Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom

C

Ceren Kütahya

Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom

P

Patrick Peschke

Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom

K

Kun Zhou

Key Laboratory of Animal Virology, Ministry of Agricultural and Rural Affairs of China and Zhejiang Provincial Engineering Research Center of Animal Biological Products, Department of Veterinary Medicine, Zhejiang University College of Animal Sciences

G

Giulia Brachi

Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom

J

Jonathan Yeow

O

Omar Rifaie‐Graham

Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom

J

Jonathan P. Wojciechowski

Department of Physiology, Anatomy and Genetics, Department of Engineering Science, Kavli Institute for Nanoscience Discovery, University of Oxford, Sherrington Rd, Oxford OX1 3QU, U.K.

T

Thomas F. F. Fernandez Debets

Department of Physiology, Anatomy and Genetics, Department of Engineering Science, Kavli Institute for Nanoscience Discovery, University of Oxford, Sherrington Rd, Oxford OX1 3QU, U.K.

V

Vernon LaLone

Department of Materials Department of Bioengineering Institute of Biomedical Engineering Imperial College London South Kensington Campus London SW7 2AZ United Kingdom

X

Xin Song

K

Krunal Polra

Department of Infectious Disease Faculty of Medicine Imperial College London South Kensington Campus London SW7 2AZ United Kingdom

P

Paul F. McKay

Department of Infectious Disease Faculty of Medicine Imperial College London South Kensington Campus London SW7 2AZ United Kingdom

J

John S. Tregoning

R

Robin J. Shattock

M

Molly M. Stevens