Shapeshifting Nanocatalyst for CO ₂ Conversion

Abstract

Abstract The conversion of CO 2 into high‐value chemicals through a photoreduction reaction in water is a promising route to reduce the dependence on fossil fuels. Enhancing selectivity toward hydrocarbons or alcohols can be achieved by Ag‐Cu alloys. However, the stabilized surface state created by Ag‐Cu interactions is still poorly understood. In this work, multi‐modal in situ X‐ray experiments reveals underlying mechanisms and the evolution of Ag‐Cu nanoparticles under CO 2 reduction reaction (CO 2 RR) conditions. Both morphological and chemical changes of Ag and Cu species induced by diffusion mechanics are tracked during nanocatalyst operation. The initial spheroid Ag‐Cu nanoparticles are composed of a Cu‐rich shell and Ag‐rich core. The reduction treatment promotes Ag migration toward the surface. During photocatalytic CO 2 reduction reaction, Cu atoms migrate back to the surface, forming Ag‐Cu‐O species. The study observes the surface oxidation of Cu(0) to Cu + and the presence of Ag at the sub‐surface region. Furthermore, nanoparticles change their shape, decreasing their specific surface area, driven by Cu diffusion during the CO 2 photoreduction reaction. The results provide invaluable insights into the dynamic restructuring of the catalyst under reaction conditions and into the active species responsible for CO 2 conversion.