Twist‐Angle Controllable Transfer of 2D Materials via Water Vapor Intercalation

X Xu Han Y Yun‐Yun Dai (School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China) P Peng‐Fei Ding (School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China) J Jie Xing (College of Materials Science and Engineering, Sichuan University , 610064 Chengdu,) T Tai‐Min Miao (Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China) Z Zhen‐Yu Sun (Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China) W Wen‐Tao Wang (Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China) D De‐Cheng Zhang (School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China) J Jia‐Hao Yan (School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China) Y Yang‐Kun Zhang (Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China) D Dong‐Ke Rong (School of Science China University of Geosciences Beijing 100083 China) Z Zi‐Hao Guo (State Key Lab of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices, South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter South China University of Technology Guangzhou 510640 P.R. China) H Hui Chen M Meng‐Ting Huang (School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China) J Jia‐Dong Zhou (School of Physics Beijing Institute of Technology Beijing 100081 China) L Luo‐Jun Du (Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China) B Bao‐Jie Feng (Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China) J Jian‐Gang Guo (Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China) G Guang‐Yu Zhang (Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China) Y Yang Chai Y Yuan Huang Y Ye‐Liang Wang (School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China)

Abstract

Abstract Transfer technique has become an indispensable process in the development of two‐dimensional materials (2DMs) and their heterostructures, as it determines the quality of the interface and the performance of the resulting devices. However, how to flexibly and conveniently fabricate two‐dimensional (2D) twisted heterostructures with high‐quality interfaces has always been a formidable challenge. Here, a quasi‐dry transfer technique assisted by water vapor intercalation (WVI) is developed, which can be flexibly used to fabricate twisted heterostructures. This method leverages a charged hydrophilic surface to facilitate WVI at the interface, enabling the clean and uniform detachment of 2DMs from the substrate. Using this method, the twisted monolayer/few‐layer graphene and 2D quasicrystal‐like WS 2 /MoS 2 , highlighting the surface/interface cleanness and angle‐controlled transfer method is successfully fabricated. Besides, suspended structures of these 2DMs and heterostructures are fabricated, which offers substantial convenience for studying their intrinsic physical properties. Further, a high‐performance hBN/graphene/hBN superlattice device with the mobility of ≈199,000 cm 2  V −1  s −1 at room temperature is fabricated. This transfer technique ingeniously combines the advantages of dry transfer and wet transfer. Moreover, it features excellent scalability, providing crucial technical support for future research on the fundamental physical properties of 2DMs and the fabrication of quantum devices with outstanding performance.

Article Details

Volume / Issue Vol. 37, Issue 19
Published May 01, 2025
ISSN 0935-9648
Publisher Unknown Publisher

Journal Info

Advanced Materials

Unknown Publisher

ISSN: 0935-9648 Physical Sciences

Authors (22)

X

Xu Han

Y

Yun‐Yun Dai

School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China

P

Peng‐Fei Ding

School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China

J

Jie Xing

College of Materials Science and Engineering, Sichuan University , 610064 Chengdu,

T

Tai‐Min Miao

Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China

Z

Zhen‐Yu Sun

Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China

W

Wen‐Tao Wang

Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China

D

De‐Cheng Zhang

School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China

J

Jia‐Hao Yan

School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China

Y

Yang‐Kun Zhang

Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China

D

Dong‐Ke Rong

School of Science China University of Geosciences Beijing 100083 China

Z

Zi‐Hao Guo

State Key Lab of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Functional and Intelligent Hybrid Materials and Devices, South China Advanced Institute for Soft Matter Science and Technology, School of Emergent Soft Matter South China University of Technology Guangzhou 510640 P.R. China

H

Hui Chen

M

Meng‐Ting Huang

School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China

J

Jia‐Dong Zhou

School of Physics Beijing Institute of Technology Beijing 100081 China

L

Luo‐Jun Du

Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China

B

Bao‐Jie Feng

Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China

J

Jian‐Gang Guo

Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China

G

Guang‐Yu Zhang

Institute of Physics and University of Chinese Academy of Sciences Chinese Academy of Sciences Beijing 100190 China

Y

Yang Chai

Y

Yuan Huang

Y

Ye‐Liang Wang

School of Integrated Circuits and Electronics Beijing Institute of Technology Beijing 100081 China